Why do flint and steel make sparks?
Correspondingly, what causes sparks in a fire?
Upon contact with oxygen in the air, the surfaces of the iron particles spontaneously ignite and give off heat as they oxidize (rust). Because the surface area of the iron particles is so large compared to their volume, the particles quickly heat up and glow red hot. They become sparks.
In respect to this, what metal makes the most sparks?
The quantity and style of sparks produced depends on the composition and pyrophoricity of the metal and can be used to identify the type of metal by spark testing. In the case of iron, the presence of carbon is required, as in carbon steel — about 0.7% is best for large sparks.
The fine wire tendrils are actually oxidising (rusting) very quickly. The same principle as a thermic lance, much hotter than normal flames (melts concrete). It has been known to cause house fires, when small pencell bateries are shorted by very fine wired articles (wire wool type pan cleaners).