Does concrete adhere to old concrete?
Moreover, does mortar stick to concrete?
Concrete, mortar or similar materials are not designed to stick or bond to old surfaces. You will not get any satisfactory results if you simply add new mortar to old. It just doesn't work. Using a modified thinset mortar would be the preferred method for this type of installation.
Thereof, can you pour new concrete over existing concrete?
Placing New Concrete Over Old. If done properly, new concrete can often be poured right over an existing slab. For this to be feasible, the contractor needs to pour at least 2 inches thick, use smaller aggregate, and incorporate reinforcement such as welded wire mesh or fiber mixed into the concrete.
Concrete resurfacer is a very strong product, rated for a compressive strength of about 4,500 psi. This is actually stronger than the slab itself, so properly applied, resurfacing layers can be very durable.